Synthesis of a Boron–Imidazolate Framework Nanosheet with Dimer Copper Units for CO <sub>2</sub> Electroreduction to Ethylene
نویسندگان
چکیده
Fundamental understanding of the dependence between structure and composition on electrochemical CO2 reduction reaction (CO2RR) would guide rational design highly efficient selective electrocatalysts. A major impediment to deep multi-carbon products is complexity carbon–carbon bond coupling. The chemically well-defined catalysts with atomically dispersed dual-metal sites are required for these C−C coupling involved processes. Here, we developed a catalyst (BIF-102NSs) that features Cl− bridged dimer copper (Cu2) units, which delivers high catalytic activity selectivity C2H4. Mechanistic investigation verifies neighboring Cu monomers not only perform as regulator varying barrier, but also afford distinct paths compared isolated monomers, resulting in greatly improved electroreduction performance CO2.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202106004